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An analytical model of through-thickness photopolymerisation of composites Ultraviolet light transmission and curing kinetics.pdf (2.124Mb)
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Title
An analytical model of through-thickness photopolymerisation of composites: Ultraviolet light transmission and curing kinetics
Author
Tena Merino, Iosu
Sarrionandia, Mariasun
Aurrekoetxea, Jon
Author (from another institution)
Sáenz Domínguez, Iván
Torre, J.
Research Group
Tecnología de plásticos y compuestos
Other institutions
Irurena Group
Version
Postprint
Rights
© 2020 Elsevier Ltd.
Access
Open access
URI
https://hdl.handle.net/20.500.11984/6375
Publisher’s version
https://doi.org/10.1016/j.compositesb.2020.107963
Published at
Composites Part B: Engineering 
Publisher
Elsevier
Keywords
polymer-matrix composites (PMCs)
cure behaviour
optical properties
analytical modelling
Abstract
In this paper, a kinetic model able to predict the evolution of the through-thickness degree of cure of ultraviolet (UV) cured composites has been developed and validated. The kinetic model, which is ... [+]
In this paper, a kinetic model able to predict the evolution of the through-thickness degree of cure of ultraviolet (UV) cured composites has been developed and validated. The kinetic model, which is based on the autocatalytic model, depends on the temperature of the composite and the absorbed intensity by the photoinitiators. This intensity is calculated by an optical model divided into discrete values of wavelength. As a result, the kinetic model considers the main factors of UV curing: the resin, reinforcement and thickness of the composite; the incident UV light spectrum; the absorbance range of photoinitiators and its consumption during the photopolymerisation. The main values of the model can be obtained by spectrometry and measuring the electric resistance of the composite during the whole UV curing process. [-]
Funder
Gobierno Vasco
Program
Ikertalde Convocatoria 2016-2021
Number
IT883-16
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Project
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