Title
FTIR as a Powerful Tool for Measurements of Diffusion in Supercritical Carbon Dioxide Using Taylor Dispersion MethodAuthor
Author (from another institution)
xmlui.dri2xhtml.METS-1.0.item-contributorOtherinstitution
https://ror.org/04z8k9a98Version
http://purl.org/coar/version/c_970fb48d4fbd8a85
Rights
© 2022 The AuthorsAccess
http://purl.org/coar/access_right/c_abf2Publisher’s version
https://doi.org/10.3390/pr10081528Published at
Processes Vol. 10. Nº. 8. Article 1528. August, 2022Publisher
MDPIKeywords
supercritical CO2
CCS
FTIR
Diffusion ... [+]
CCS
FTIR
Diffusion ... [+]
supercritical CO2
CCS
FTIR
Diffusion
toluene
benzene [-]
CCS
FTIR
Diffusion
toluene
benzene [-]
Abstract
A new experimental high-pressure setup for measuring diffusion coefficients in supercritical fluids, based on Taylor dispersion method, and using an FTIR detector to operate up to 25.0 MPa was designe ... [+]
A new experimental high-pressure setup for measuring diffusion coefficients in supercritical fluids, based on Taylor dispersion method, and using an FTIR detector to operate up to 25.0 MPa was designed and optimized. Tracer diffusivities, D12, of toluene and benzene in supercritical carbon dioxide were measured in the temperature range of 306.15–320.15 K, and pressure range of 7.5–17 MPa to evaluate the setup and experimental protocol. The effects of flow velocity, volume of the cell, absorbance at different wavenumbers on the diffusion coefficient as well as all parameters respecting the Taylor dispersion method have been analyzed. The obtained diffusion coefficients are in excellent agreement with the available literature data. The dependence of D12 on temperature, pressure, and solvent density were examined. Some correlation models based on the hydrodynamic theory were used to estimate the diffusion coefficients in supercritical carbon dioxide, which is the best agreement obtained for an improved version of the Wilke–Chang model. [-]
xmlui.dri2xhtml.METS-1.0.item-sponsorship
Comisión Europeaxmlui.dri2xhtml.METS-1.0.item-projectID
info:eu-repo/grantAgreement/EC/Fondo Europeo de Desarrollo Regional (FEDER)/POCI-01-0145-FEDER-030271/EU/Difusão Molecular e Difusão Térmica de CO2 em misturas modelo próximo do ponto crítico/KIDIMIXCollections
- Articles - Engineering [639]
The following license files are associated with this item: