2026-04-23T15:40:06Zhttps://ebiltegia.mondragon.edu/oai/request

oai:ebiltegia.mondragon.edu:20.500.11984/60522024-03-04T13:48:23Zcom_20.500.11984_473col_20.500.11984_478

Shevtsova, Valentina 2023-03-21T13:55:26Z 2023-03-21T13:55:26Z 2023 1420-3049 https://katalogoa.mondragon.edu/janium-bin/janium_login_opac.pl?find&ficha_no=171778 https://hdl.handle.net/20.500.11984/6052 Experimental binary diffusion coefficients for short-chain alcohols in supercritical carbon dioxide were measured using the Taylor dispersion technique in a temperature range of 306.15 K to 331.15 K and along the 10.5 MPa isobar. The obtained diffusion coefficients were in the order of 10−8 m2 s−1. The dependence of D on temperature and solvent density was examined together with the influence of molecular size. Some classic correlation models based on the hydrodynamic and free volume theory were used to estimate the diffusion coefficients in supercritical carbon dioxide. Predicted values were generally overestimated in comparison with experimental ones and correlations were shown to be valid only in high-density regions. eng Attribution 4.0 International http://creativecommons.org/licenses/by/4.0/ © 2023 The Authors supercritical CO2 FTIR Taylor dispersion technique methanol ethanol propanol butanol Widom line Binary Diffusion Coefficients for Short Chain Alcohols in Supercritical Carbon Dioxide-Experimental and Predictive Correlations http://purl.org/coar/resource_type/c_6501