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Title
Role of specific interactions on fiber formation in the electrospinning of poly (vinyl phenol)/ poly (vinyl pyrrolidone) blend solutions
Author
Buruaga, Lorea
Muñoz, M. E.
Irusta, Lourdes
González, Alba
Iruin, Juan José
Other institutions
Universidad del País Vasco/Euskal Herriko Unibertsitatea (UPV/EHU)
Version
Published version
Rights
© 2009 Wiley Periodicals,
Access
Embargoed access
URI
https://hdl.handle.net/20.500.11984/7000
Publisher’s version
http://doi.org/10.1002/app.30849
Published at
Journal of Applied Polymer Science  Vol. 114. Nº 5. December 2009
xmlui.dri2xhtml.METS-1.0.item-publicationfirstpage
2922
xmlui.dri2xhtml.METS-1.0.item-publicationlastpage
2928
Publisher
Wiley
Abstract
The minimum concentration (Ci) required for electrospinning polymeric fibers from solutions of mixtures of poly(vinyl phenol) and poly(vinyl pyrrolidone) has been experimentally determined for differe ... [+]
The minimum concentration (Ci) required for electrospinning polymeric fibers from solutions of mixtures of poly(vinyl phenol) and poly(vinyl pyrrolidone) has been experimentally determined for different blend compositions. This minimum concentration Ci has its lowest value when the polymers are mixed in a 1/1 molar ratio. This article shows different results that seem to indicate that the strong hydrogen bonding interactions between the two polymers and the corresponding higher apparent molecular weight cause the reduction of the Ci value. [-]
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