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Anisotropic nanoparticle-based magnetorheological elastomers Effect of shape and orientation on the magnetorheological performance.pdf (2.963Mb)
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Title
Anisotropic nanoparticle-based magnetorheological elastomers: Effect of shape and orientation on the magnetorheological performance
Author
García Díez, Ander
Rial Tubio, Carmen
Gómez, Ainara
Berasategi Arostegi, Joanes
Insausti, Maite
Garitaonandia, José S.
Bou-Ali, M. Mounir
Gutierrez Etxebarria, Jon
Lanceros-Mendez, Senentxu
Research Group
Mecánica de fluidos
Other institutions
Universidad del País Vasco/Euskal Herriko Unibertsitatea (UPV/EHU)
Basque Center for Materials, Applications and Nanostructures
Ikerbasque
Version
Published version
Rights
© 2024 Elsevier Ltd
Access
Embargoed access
URI
https://hdl.handle.net/20.500.11984/6951
Publisher’s version
https://doi.org/10.1016/j.polymer.2024.126776
Published at
Polymer  Vol. 295. N. art. 126776, 2024
Publisher
Elsevier
Keywords
Smart materials
Anisotropic nanocomposites
Magnetic properties
Mechanical properties
Abstract
Magnetorheological elastomers (MREs) respond to applied magnetic fields with a change in their mechanical properties. Within this work, iron oxide nanorods (IONRs) have been synthesized and the suitab ... [+]
Magnetorheological elastomers (MREs) respond to applied magnetic fields with a change in their mechanical properties. Within this work, iron oxide nanorods (IONRs) have been synthesized and the suitability of anisotropic nanoparticles to obtain highly responsive isotropic and anisotropic MREs has been demonstrated. Electron microscopy images show that the IONRs are well distributed inside the styrene-ethylene-butylene-styrene (SEBS) polymeric matrix and can be successfully oriented. The elastic modulus of the composites increases twofold with respect to the bare polymer. Room temperature magnetization loops of the composites show a difference in the orientations, with variations of the anisotropy field from 39.2 kA m−1 to 67.7 kA m−1. Magnetorheology measurements show that the relative magnetorheological effect experiences a twofold increase for the anisotropic MREs, from 8.3% to 17%. This, along with the improved mechanical properties of the anisotropic MREs, offers excellent possibilities for the design of high performance MREs that work optimally in the elastic region and possess improved applicability. [-]
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